DYNAMIC INTERACTIONS: A STUDY OF VISCOSITIES AND EXCESS THERMODYNAMIC PROPERTIES IN CYCLIC ETHER-1-ALKANOL SYSTEMS
Abstract
Over the past three decades, the ultrasonic study of liquid mixtures has emerged as a pivotal avenue for unraveling molecular interactions and exploring the physicochemical behavior inherent in such systems. This paper delves into the importance of ultrasonic techniques, focusing on their profound role in comprehending molecular interactions and investigating the departure of liquid mixtures from ideality. Thermodynamic and transport properties, widely utilized for studying liquid mixtures, serve as key indicators of the intricate intermolecular forces and size differences within these systems. The exploration of excess thermodynamic functions forms a cornerstone in understanding the nuanced molecular interactions and structural changes exhibited by binary liquid mixtures. Sensitivity to variations in both intermolecular forces and molecular sizes, excess thermodynamic functions play a crucial role in deciphering deviations from ideal behavior. Fundamental properties like internal pressure and free volume, initially investigated by Hildebrand and Scott, serve as pivotal parameters in studying molecular interactions within liquid mixtures. Utilizing ultrasonic velocity, viscosity, and density measurements, this study employs a multidimensional approach to unravel the molecular intricacies of liquid mixtures. The insights gained from measuring these properties are not only significant for studying the departure of real liquid mixtures from ideal behavior but also for comprehending the structural changes associated with these dynamic systems. The paper underscores the importance of ultrasonic techniques in providing a comprehensive understanding of liquid mixtures, shedding light on their thermodynamic and transport properties, and facilitating insights into the molecular interactions governing their behavior.
Keywords:
Ultrasonic Study, Liquid Mixtures, Excess Thermodynamic Functions, Molecular Interactions Physicochemical BehaviorDownloads
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https://doi.org/10.5281/zenodo.10534499%20Issue
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Copyright (c) 2024 Priya Anjali Sharma
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